Uranium has 16 isotopes, all of which are radioactive. The isotope
235U is used in nuclear reactors because it
can be made to release large amounts of energy to boil water into
steam that expands to drive
steam turbines
that, in turn, drive electrical generators.
One pound of pure fisssionable uranium equals
the energy derived from burning 1500 tons of coal. Depleted uranium; that is, uranium
with less than 0.2% of 235U, which is extremely dense, is used in
inertial guidance systems, gyro compasses, shielding material, and ammunition.
Lide 4-31
Uranium was discovered in 1786 in pitchblende ore by Martin Heinrich Klaproth, a German
chemist. It was isolated in 1841 by Peligot, who
reduced the anhydrous chloride with
potassium.
Uranium is found in pitchblende,
uraninite, carnotite,
autunite, uranophane,
davidite, tobernite,
phosphate rock, lignite, and
monazite. Uranium is prepared by reducing uranium
halides with alkali or alkaline earth metals, or by reducing uranium oxides by
calcium, aluminum,
or carbon at high temperatures. It can also be obtained by
electrolysis of
KUF5 or UF4 dissolved in a molten
mixture of CaCl2 and NaCl.
High purity uranium is prepared by the thermal decomposition of uranium halides on a hot filament.
Lide 4-31
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