Large commercial quantities
of hydrogen are required for the fixation of nitrogen in the
Haber Process for making ammonia, for the
hydrogenation and dehydrogenation of fats and
oils, and for methanol production, hydrodealkylation (adding hydrogen to remove an alkyl
group) , hydrocracking (adding hydrogen to break up large petroleum molecules),
hydrodesulfurization (adding hydrogen to remove sulfur). Hydrogen also is used as a
rocket fuel, in welding, in the production of
hydrochloric acid (HCl), in
cryogenic reseach, superconductivity studies and the reduction of metallic ores.
Two hydrogen isotopes are useful:
Deuterium (two neutrons) water,
D2O, is used as a moderator to slow down neutron activity in
nuclear reactors and a fuel in
fusion reactors. Tritium (three neutrons) is used
to produce luminous paints and tracers and as a fuel in fusion reactors.
(It also is used to make hydrogen bombs.)
Lide 4-14
Hydrogen is essential to all plant and animal life as
water, which permeates the entire organism to serve as a medium for
cellular biochemical reactions and transportation. Hydrogen forms hydrochloric acid
used by the animal stomach for digestion and it forms hydrocarbon molecules that comprise
plant and animal structures, organs, cells, and cell organelles.
Hydrogen was recognized as a a separate substance by Cavendish in 1766 and named
by Antoine-Laurent Lavoisier, the famous French chemist. Hydrogen exists on earth as
water, H2O, and, as hydrocarbons, in
all organic matter, such as living plants, coal, and
petroleum. Minute amounts of hydrogen are
contained in the atmosphere. Hydrogen is prepared by the action
of steam on hot carbon, by the
decomposition of hydrocarbons (molecules of hydrogen and carbon) with heat, by the
electrolysis of water, by the displacement from acids by
some metals, and by the action of sodium hydroxide, NaOH, or
potassium hydroxide, KOH, on
aluminum.
Lide 4-14
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